Does Hot Water Freeze Faster Than Cold Water?

Determining whether or not hot water can freeze faster than cold water may seem like a no-brainer. After all, water freezes at 0 degrees Celsius. And wouldn’t water hot enough to kill E. coli bacteria (about 120 degrees Fahrenheit or 50 degrees Celsius) take a longer path than cooler water at a fall New England beach (about 60 degrees Fahrenheit or 15 degrees Celsius) towards a frigid future as ice? While a logical assumption, it turns out that hot water can freeze before cooler water under certain conditions.

This apparent quirk of nature is the "Mpemba effect," named after the Tanzanian high school student, Erasto Mpemba, who first observed it in 1963. The Mpemba effect occurs when two bodies of water with different temperatures are exposed to the same subzero surroundings and the hotter water freezes first. Mpemba’s observations confirmed the hunches of some of history’s most revered thinkers, such as Aristotle, Rene Descartes and Francis Bacon, who also thought that hot water froze faster than cold water.

Evaporation is the strongest candidate to explain the Mpemba effect. As hot water placed in an open container begins to cool, the overall mass decreases as some of the water evaporates. With less water to freeze, the process can take less time. But this doesn’t always work, especially when using closed containers that prevent evaporated water from escaping.
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